Hakuouki

土方歳三

Hijikata is the one who orders Chizuru to be taken to the Shinsengumi headquarters for questioning, and he is the one Chizuru instantly notices. His role in the squad is to be the fierce Demon Vice-Commander, whom everyone respects and fears. Despite being Kondou's subordinate, Hijikata is the one who makes most decisions in the Shinsengumi, often asking for Kondou's opinion or approval. However, he never tries to officially take the lead away from Kondou and never disobeys his command. His goal is to make Kondou a General despite them both not being born into samurai families. Additionally, he treats all the Shinsengumi members as true warriors regardless of their background and holds them to a high standard.

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風間千景

Kazama is a fictional character who does not have a historical counterpart. He is introduced in the anime storyline during the Ikedaya Incident, when he defeats Okita, but his actual sworn enemy is Hijikata, as the two continue encountering each other in various settings. Kazama is often followed by his vassal Amagiri and sometimes joins forces with Shiranui, who has his own agenda but does not mind participating in Kazama's plans. Kazama's main goal is to marry Chizuru, as she is a female pure-blooded demon who can give birth to powerful offspring.

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雪村千鶴

Chizuru is the daughter of a respected doctor from Edo. Shortly before the beginning of the story, her father leaves home and travels to Kyoto, regularly sending her letters. However, one day, the letters stop, and Chizuru decides to embark on a journey to find her father. Upon her arrival in Kyoto, she is harassed by rogue samurai who take an interest in her sword, and, as she runs away, she encounters mysterious creatures, only to be saved by the Shinsengumi.

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原田左之助

Sano is introduced along with the other Shinsengumi captains when Chizuru is brought in for questioning. He is often seen as part of the trio, along with Heisuke and Shinpachi, who enjoy fighting and drinking together, often breaking Hijikata's rules and curfew. Sano is very popular with women and is good at understanding girls' hearts, and he is noticed and adored by geishas at Shimabara. Despite having a flirty personality and a reputation as a ladies' man, Sano is extremely honorable. He treats his opponents with respect and never tries to find excuses for his actions. In his own words, men should not look for excuses.

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藤堂平助

Heisuke is introduced along with the other Shinsengumi captains when Chizuru is brought in for questioning. He is often seen as part of a trio, along with Sano and Shinpachi, who enjoy fighting and drinking together, frequently breaking Hijikata's rules and curfew. Heisuke often has to fight Shinpachi for his food, creating chaos in the common room and provoking the Vice-Commander.

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永倉新八

Shinpachi is introduced along with the other Shinsengumi captains when Chizuru is brought in for questioning. He is often seen as part of the trio (along with Heisuke and Sano) who enjoy fighting and drinking together, often breaking Hijikata's rules and curfew. Despite his goofy attitude, Shinpachi understands politics quite well and knows exactly what his convictions are. He is not afraid to question orders or express his disapproval. However, he is not particularly fortunate with women, which is why he is envious of Sano's luck and often asks him for advice.

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不知火匡

Shiranui is a fictional character and does not have a historical counterpart. He has his own interests, but he often joins Kazama in his attempts to kidnap Chizuru from the Shinsengumi, as he finds it entertaining.

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山南敬助

Sannan is introduced along with the other Shinsengumi captains when Chizuru is brought in for questioning. He is often seen isolated in his room, researching and conducting experiments, while other members of the squad consider him aloof and intimidating. As one of the Vice-Commanders and a scientist, Sannan is a smart and educated man, which is why others often listen to his opinion. Sannan also stands out due to being the only one who wears glasses even in combat.

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近藤勇

Kondou is introduced along with the other Shinsengumi captains when Chizuru is brought in for questioning. He is an amiable, slightly older-looking man who often laughs and treats everyone with warmth and care. He is close friends with Hijikata, as they spent most of their youth together and shared the same hopes and dreams of becoming warriors despite not being born into samurai families. Kondou also deeply loves Souji, whom he raised from an abandoned child into a fearless warrior.

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島田魁

Shimada has a rather square-jawed face with dark brown hair and is always seen wearing his Shinsengumi haori over a purple shirt and green trousers. He seems to be a competent warrior who relies on his brute physical strength, and he looks much older than the other Shinsengumi members.

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